Yes, you can. Go to settings page and there are options for setting up queue publishing hours, which we call “Timepoints”. You can setup your own timepoints for each of connected profiles/pages/accounts!

Queue settings view
Yes, you can. Go to settings page and there are options for setting up queue publishing hours, which we call “Timepoints”. You can setup your own timepoints for each of connected profiles/pages/accounts!
Queue settings view